Hi, thanks for posting!
I'm afraid that NCrunch currently does not support custom ExpectedException attributes for the MSTest framework.
This is due to limitations in the way that NCrunch is able to interoperate with this framework. Because NCrunch's MSTest adapter only emulates MSTest (rather than calling it directly), not all features of the framework can be made available. I recommend implementing an alternative method for inspecting exceptions, such as a try->catch block within the test itself.
Cheers,
Remco